# The Azimuth Project Blog - a quantum of warmth (Rev #14, changes)

Showing changes from revision #13 to #14: Added | Removed | Changed

This page is a blog article in progress, written by Tim van Beek.

#### The Case of the Missing 33 Kelvin Continued

Last time, when we talked about putting the Earth in a box, we saw that a simple back-of-the-envelope calculation about the energy balance and the resulting average temperature of the earth is surprisingly close to the real world. But there is a gap: The temperature predicted by a zero dimensional energy balance mode is about 33 Kelvin lower than the estimated average surface temperature on earth.

In such a situation, as theoretical physicsists, we congratulate ourselves on a successful first approximation, , and look out for the next most important effect that we need to include in our model.

Most of you will of course heard about the effect that climate scientists talk about, which is often - but confusingly - called “greenhouse effect”, or “back radiation”. The term that is most accurate is downward longwave radiation (DLR), however, so I would like to use that instead. But first we’ll have to peek into our simple model’s box and figure out what is going on in there in more detail.

#### Peeking into the Box and Splitting up: Surface and Atmosphere

To get a better approximation, instead of treating the whole earth as a black body, we’ll have to split up the system into earth itself, and its atmosphere. For the surface of the earth it is still a good approximation to say that it is a black body.

The atmosphere is more complicated. In a next approximation step, I would like to pretend that the atmosphere is a body of its own, hovering above the surface of the earth, as a separate system. So we will ignore that there are several different layers in the atmosphere doing different things, including interactions with the surface. Okay, we are not going to ignore the interaction with the surface completely, as you will see.

Since one can quickly get lost in details when discussing the atmosphere, I’m going to cheat and look up the overall average effects in an introductory meteorology textbook:

• C.Donald Ahrens: Meteorology Today, 9th edition, Books/Cole 2009.

Here is what atmosphere and Earth’s surface do to the incoming radiation from the sun (from page 48):

Of 100 units of inbound solar energy flux 30 are reflected or scattered back to space without a contribution to the energy balance of the Earth. This corresponds to an overall average albedo of 0.3 of the Earth.

The next graphic shows the most important processes of heat and mass transport caused by the remaining 70 units of energy flux, with their overall average effect (from page 49):

Maybe you have some questions about this graphic; I certainly do.

#### Conduction and Convection?

Introductory classes for partial differential equations sometimes start with the one dimensional heat equation: This equation describes the temperature distribution of a rod of metal that is heated on one end and kept cool on the other. The kind of heat transfer occurring here is called conduction. The atoms or molecules stay where they are and transfer energy by interacting with their neighbours.

Heat transfer by conduction is negligible for gases like the atmosphere; why is it there in the graphic? The answer is that conduction is still important for boundary layers. So, we don’t forget boundary layer interaction completely, as I promised.

#### What is Latent Heat?

There is a label “latent heat” on the left part of the atmosphere: Latent heat is energy input that does not result in a temperature increase, or energy output that does not result in a temperature decrease. This can happen, for example, when there is a phase change of a component of the system: When fluid water at 0°C freezes, it turns into ice at 0°C while losing energy to its environment. But the temperature of the whole system stays at 0°C.

The picture above shows a forest with water vapor (invisible), fluid (dispersed in the air) and snow. As the sun sets, parts of the water vapor will eventually turn into ice, releasing energy to the environment. During the phase changes there will be energy loss without a temperature decrease of the water.

#### Downward Longwave Radiation: The Atmosphere is not a Black Body

Last time we pretended that the Earth as a whole behaves like a black body.

But you may notice that

a) a lot of sunlight passes through the atmosphere and reaches the surface and

b) there is a lot of energy flowing downwards from the atmosphere to the surface in form of infrared radiation. This is called downward longwave radiation. Observation a) shows that the atmosphere does not act like a black body at all. Instead, it has a nonzero transmittance, which means that not all incoming radiation is absorbed.

Observation b) shows that asumming that the black body temperature of the Earth is equal to the average surface temperature could go wrong, because - from the viewpoint of the surface - there is an additional inbound energy flux from the atmosphere.

The reason for both observations is that the atmosphere consists of a couple of different gases, like $0_2, N_2$ and $CO_2$. These molecules can absorb and emit radiation at certain frequencies only. This observation lead to the development of quantum mechanics, which can be used to calculate the characteristic emission spectrum for every molecule.

#### Molecules and Degrees of Freedom

When a photon hits a molecule, the molecule can absorb the photon either by

• an electron climbing the stairs to a higher energy level,

• stronger vibration or

• stronger rotation.

To get a first impression of the energy levels involved in these three processes, let’s have a look at this graphic:

This is taken from the book

• Sune Svanberg: “Atomic and Molecular Spectroscopy”, Springer, 4th edition

The energy on the Y-axis is measured in electron volt: This is the energy that an electric charge takes up when it travels across an electric potential difference of one volt.

Accoding to quantum mechanics, a molecule can emit and absorb only photons whose energy matches the difference of one of the discrete energy levels in the graphic, for either one of the three processes.

It is possible to use the characteristic absorption and emission properties of molecules of different chemical species to analyze the chemical composition of an unknown probe of gases (and other materials, too). These methods are usually called names involving the word spectroscopy, like, for example, infrared spectroscopy for methods that examine what happens to infrared radiation when you send it to your probe.

By the way, Wikipedia has a funny animated picture with the different vibrational modes of a molecule on the page infrared spectroscopy.

#### Downward Longwave Radiation: No Infrared From the Sun

The reason why so much of the radiation of the sun passes through, but a lot of infrared radiation does not but flows back to the surface, involves the specific property of certain components of the atmosphere.

But first things first: Here is a nice overview of the spectrum of electromagnetic radiation:

From the Planck distribution, we can determine that sun and earth, as black bodies, emit radiation mostly at very different wavelenghts:

This graphic is sometimes called “twin peak graph”.

The Earth emits mostly infrared radiation; the sun emits almost no infrared.

Only some components of the atmosphere emit and absorb radiation in the infrared part. These are called - somewhat misleading - greenhouse gases . I would like to call them “IR-active gases” instead, but unfortunately the “greenhouse gas” misnomer is very popular. Two prominent ones are$H_2O$ and $CO_2$:

The atmospheric window at 8 to 12μm is quite transparent, which means that this radiation passes from the surface to through the atmosphere into space without much ado. Therefore, this window is used by satellites to estimate the surface temperature.

It is not a coincidence that molecules with different species like $CO_2$ react to infrared radiation, while those with one kind of atom like $O_2$ do not. The deeper reason is that molecules with different species may have a dipole moment.

Since most radiation coming from the Earth is infrared, and only some constituents of the atmosphere react to it - excluding the major ones - a small amount of, say, $CO_2$ could have a lot of influence on the energy balance. Like being the only one in a group of hundreds with a boom box. But we should check that more thoroughly.

#### Can a Cold Body Warm a Warmer Body?

Downward longwave radiation warms the surface, but: The atmosphere is colder than the surface, so how can radiation from the colder atmosphere result in a higher surface temperature? Doesn’t that violate the second law of thermodynamics?

The answer is: No it does not. It turns out that others have already taken pains to explain this on the blogosphere, so I’d like to point you there instead of trying to do a better job here:

#### It's the Numbers, Stupid!

Maybe we have succeeded by now to convince the imaginary advisory board of the zero dimensional energy balance model project that there really is an effect like “downward longwave radiation”. It certainly should be there if quantum mechanics is right. The problem is that we do not have any idea how big it is. According to “Meteorology Today”, it is big. But maybe the people who contributed to the graphic got fooled somehow; and there really is a different explanation for the case of the missing 33 Kelvin.

What do you think?

category: blog